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A história mostra que nada é totalmente novo e que por isso o antigo não deve ser descartado e sim conhecido para que novos conhecimentos sejam construídos. Assim, quando entrevistado por Rudy M. Baum, Henry Taube, Prêmio Nobel de Química de 1983, disse que foi um erro o desaparecimento da análise qualitativa dos currículos das universidades norte-americanas, porque esta constituía um meio de introduzir a química descritiva e de motivar os alunos a estudarem as reações químicas que, em sua opinião, “são o coração da química” [1]. Em vista desta polêmica e das possíveis opções para o emprego da disciplina de Química Analítica Qualitativa como ferramenta para o ensino básico dos equilíbrios químicos em solução aquosa, apresenta-se a seguir uma visão crítica da seqüência histórica do desenvolvimento dos procedimentos de análise qualitativa.Referências
Baum, R. M., Henry Taube Wins ACS’s Highest Award in Chemistry, Chem. Eng. News, 1984, 62: 31.
Stubbs, M. F., Qualitative Analysis in the General Chemistry Program, J. Chem. Educ., 1959, 36: 387.
Hovey, N. W., The Present and Future of Qualitative Analysis. J. Chem. Educ., 1963, 40: 410.
Toby, S., What’s Present? Qualitative Analysis Problems in General Chemistry. J. Chem. Educ., 1995, 72: 1008-1009.
Laitinen, H. A., Analytical Chemistry in a Changing World, Anal. Chem., 1980, 52: 605A.
Benedetti-Pichler, A. A.;Schneider, F.; Steinbach, O. F., Qualitative Analysis in the Training of Chemists. J. Chem. Educ., 1957, 34: 381.
Frank, R. E., Identification Analysis, A Stimulating Revival of Qualitative Analysis. J. Chem. Educ., 1957, 34: 382.
Senise, P. E. A., A Química Analítica na Formação do Químico. Quim. Nova, 1982, 5: 137-143.
Szabadváry, F., History of Analytical Chemistry, Londres, Pergamon Press, 1966.
Hillis, M. O., The History of Microanalysis. J. Chem. Educ., 1945, 22: 348.
Farmacopéia Brasileira, 4ª. ed, São Paulo, Atheneu, 1988.
Welcher, F. J., History of Qualitative Analysis. J. Chem. Educ., 1957, 34: 389.
Kolthoff, I. M., Development of Analytical Chemistry as a Science. Anal. Chem., 1973, 45: 24A.
Beck II, C. M., Classical Analysis – A Look at the Past, Present, and Future. Anal. Chem., 1994, 66: 224A.
Rose, H., Traité Complet de Chimie Analytique, Paris, Librairie de Victor Masson, 1859.
Fresenius, W. (Rev.) Fresenius, C. R. – Traité D’Analyse Chimique Qualitative, 17th ed., Paris, Masson et Cie, 1922.
Pearson, T. H.; Ihde, A. J., Chemistry and the spectrum before Bunsen and Kirchhoff. J. Chem. Educ., 1951, 28: 267.
Kirchhoff, G.; Bunsen, R., Chemical Analysis by Observation of Spectra. Annalen der Physik und der Chemie, 1860, 110: 161.
Chamot, E. M.; Mason, C.W., Chemical Microscopy. II.Its Value in the Training of Chemists. J. Chem. Educ., 5, 258, 1928.
van Nieuwenburg, C. J., Modern Qualitative Analysis and Industrial Practice. Analyst, 1956, 81: 450.
Feigl, F.; Anger , V., Spot Tests in Inorganic Analysis, 6th ed., Amsterdam, Elsevier Publishing Company, 1972.
Feigl, F.; Stern, R., The Application of Spot Reactions in Qualitative Analysis. Z.Anal. Chem., 1921, 60, 1. (CA 15: 2598).
Feigl, F.; Neuber, F., The Detection of the Elements of the Hydrogen Sulfite with Particular Regard to Spot Reactions. Z. Anal. Chem., 1923, 62: 373. (CA 17: 2687).
Feigl, F.; Anger, V., Spot Tests in Organic Analysis, 7th ed., Amsterdam, Elsevier Publishing Company, 1966.
Haimberger, L., A vida e obra de Fritz Feigl, Quím. Nova, 1983, 6:55-60.
Espínola, A., Fritz Feigl – sua obra e novos campos tecno-científicos por ele originados, Quím. Nova, 2004, 27:169-176.
Tananaeff, N. A., Qualitative Analysis of the Elements of the First to Third Groups when Present Together, with Special Regard to Spot Tests. Z. Anorg. Allgem. Chem., 1924, 140: 320 (CA, 19, 1108).
van Nieuwenburg, C. J., Systematical Qualitative Analysis by Means of Modern Drop Reactions. Mikrochemie, 1931, 3: 199 (CA, 25, 2935).
Davies, W. C., A Scheme for Qualitative Chemical Analysis Employng Spot Tests. J. Chem. Educ., 1940, 17: 231.
Benedetti-Pichler, A. A., Qualitative Analysis of Microgram Samples. Ind. Eng. Chem., Anal. Ed., 1937, 9: 483.
Tschugaeff, L., Ueber ein neues, empfindliches Reagens auf Nickel. Ber., 1905, 38: 2520.
Brunck, O., Use of Dimethylglyoxime for Determination of Nickel. Z. Angew. Chem., 20, 3844, 1907 (CA 2, 240).
West, P. W.; Vick, M. M., Qualitative Analysis and Analytical Chemical Separations without the Use of Sulfites. J. Chem. Educ., 1957, 34: 393.
Lumme, P.; Tummavuori, J., Phthalic Acid as a Reagent in Inorganic Qualitative Analysis of MetalIons.1. New System for Qualitative Analysis. Acta Chem. Scand., 1973, 27: 851.
Sanyal, S., Separating Copper from Cadmium without Cyanide. J. Chem. Educ., 1959, 36: 387.
Chandra, R., Non-Cyanide Detection of Cadmium in the Presence of Copper. J. Chem. Educ., 1961, 38: 409.
Whitehead, T. H.; Hatcher, G. K., The Separation and Identification of Cadmium and Copper Ions. J. Chem. Educ., 1962, 39: 399.
Abrão, A., Separation and Identification of Copper in the Presence of Cadmium. J. Chem. Educ., 1963, 40: 413.
Chakraborty, A.; Chakraborty, A.; Chakravarti, A. K., Detection of Copper(II) and Cadmium(II) without Cyanide in Qualitative Analysis. J. Indian. Chem. Soc., 2002, 79: 19.
Thompson, M. L.; Bixler, J. W., Abridged Qualitative Analysis with Limited Reagents. J. Chem. Educ., 1971, 48: 113.
Lambert, J. L.; Meloan, C. E., A Simple Qualitative Analysis Scheme for Several Environmentally Important Elements. J. Chem. Educ., 1977, 54: 249- 252.
Haendler, B. L.; Cook, R.; Siemiencow, G., An Individualized Approach to Qualitative Analysis. J. Chem. Educ., 1982, 59: 333-334.
Petty, J. T., A Short Qualitative Analysis Scheme without Hazardous Wastes. J. Chem. Educ., 1991, 68: 942-943.
Solomon, S.; Fülep-Poszmik, A.; Lee, A., Qualitative Analysis of Eleven Household Compounds. J. Chem. Educ., 1991, 68: 328-329.
Tan, Y. S. S.; Tan, B. H. I. ; Lee, H. K. ; Yan, Y. K.; Hor, T. S., A. Designing a Self-Contained Qualitative Analysis Test for Transition Metal Ions. J. Chem. Educ., 1998, 75: 456-458.
Reed, R. D.; Cortelyou, W. P.; Calandra, A., Aims or Objectives of Qualitative Analysis. J. Chem. Educ., 1940, 17: 220.
Bacon, E. K.; Heath, F. H.; Martin, C. S.; Reed, R. D.; Rogers, H. W.; Weidner, B. V., Qualitative Analysis in College Chemistry. J. Chem. Educ., 1950, 27: 675.
Krohn, A., What Has Happened to Qualitative Analysis? A 1966 Survey. J. Chem. Educ., 1966, 43: 419.
Wasley, W. L., The Objectives of Qualitative Analysis. J. Chem. Educ., 1946, 23: 357.
Swift, E. H., A Proposal for a Reversal of Trends. J. Chem. Educ., 1950, 27: 677.
Strong III, F. C., The Qualitative Analysis Course Should Teach Analysis. J. Chem. Educ., 1957, 34: 400.
Freiser, H., Why Teach Qualitative Analysis. J. Chem. Educ., 1957, 34: 387.
Woodfield, B. F. ; Catlin, H. R.; Waddoups, G. L.; Moore, M.S.; Swan, R.; Allen, R.; Bodily, G., The Virtual Chemlab Project: A Realistic and Sophisticated Simulation of Inorganic Qualitative Analysis. J. Chem. Educ., 2004, 81: 1672-1678.
Tan, K. C. D.; Goh, N. K.; Chia, L. S.; Treagust, D. F., Major Sources of Difficulty in Students’ Understanding of Basic Inorganic Qualitative Analysis. J. Chem. Educ. 2004, 81: 725-732.
Cunniff, P. A., (Ed.) Official Methods of Analysis of AOAC International. AOAC INTERNATIONAL. 3rd revision, 16th ed., Gathersburg, 1997.
American Society for Testing and Materials. ASTM Standards Source CD. West Conshohocken, 2003.
Afonso, J. C.; da Silveira, J. A.; Oliveira, A. de S.; Lima, R. M. G., Análise Sistemática de Reagentes e Resíduos sem Identificação. Quim. Nova 2005, 28: 157-165.
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