Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction
n. 26 (2018), Resumos
n. 26 (2018)

Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction

Resumos
https://doi.org/10.20396/revpibic262018885
Publicado 2019-02-12
Lucas Grijó dos Reis
Universidade Estadual de Campinas
Fernando Antonio Santos Coelho
Universidade Estadual de Campinas
Lucas André Zeoly
Universidade Estadual de Campinas
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Palavras-chave

Morita-Baylis-Hillman
Lewis bases
Organocatalysis.

Como Citar

REIS, Lucas Grijó dos; COELHO, Fernando Antonio Santos; ZEOLY, Lucas André. Design of poly-functionalized catalysts and additives for the Morita-Baylis-Hillman reaction. Revista dos Trabalhos de Iniciação Científica da UNICAMP, Campinas, SP, n. 26, 2019. DOI: 10.20396/revpibic262018885. Disponível em: https://econtents.bc.unicamp.br/eventos/index.php/pibic/article/view/885. Acesso em: 20 abr. 2024.
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Resumo

In this work we developed a new syntetic approach for the preparation of bi-functional catalysts derived from imidazole, without conformational constraints and having a center acting as Lewis base and other as Bronsted acid. These new catalysts were prepared in three steps, in overall yields ranging from 15% to up 48%, using Morita-Baylis-Hillman adducts as building blocks.

https://doi.org/10.20396/revpibic262018885
PDF (English)

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